Dichlorido(methanol-κO)[2-(2-pyridylmethoxy)-1,10-phenanthroline-κ3 N,N′,N′′]manganese(II)
نویسندگان
چکیده
In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa-hedral geometry. There is a π-π stacking inter-action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crystal structure also contains weak inter-molecular O-H⋯Cl hydrogen bonds that link neighboring complex mol-ecules into a one-dimensional chain along the b axis.
منابع مشابه
mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ3 S,N 1,O)(methanol-κO)(1,10-phenanthroline-κ2 N,N′)nickel(II)
In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octa-hedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thio-semicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N-H⋯Cl, N-H⋯N, C-H⋯S and O-H⋯S hydrogen bonds.
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The title compound, [Pb(2)(C(7)H(5)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], crystallizes as a dinuclear centrosymmetric dimer containing two Pb(II) atoms bridged by two benzoate ligands. Each Pb(II) atom is seven-coordinated by a water mol-ecule, a nitrate anion, a 1,10-phenanthroline (phen) ligand and two benzoate anions. The crystal packing is stabilized by O-H⋯O hydrogen bonds and by...
متن کاملPoly[[tetra-μ-cyanido-κ8 C:N-dodeca-cyanido-κ12 C-tris(N,N-dimethylformamide-κO)tris(methanol-κO)tris(3,4,7,8-tetramethyl-1,10-phenanthroline-κ2 N,N′)trimanganese(II)ditungstate(V)] dihydrate]
The asymmetric unit of the title compound, {[Mn3{W(CN)8}2(C16H16N2)3(C3H7NO)3(CH3OH)3]·2H2O} n , consists of three [Mn(N,N-di-methyl-formamide)(methanol)(3,4,7,8-tetra-methyl-1,10-phenanthroline)](2+) cations, two [W(CN)8](3-) anions and two water mol-ecules. Each water mol-ecule is disordered over three sets of sites, with a refined occupancy ratio of 0.310 (9):0.275 (9):0.415 (9) for one mol-...
متن کاملChloridobis(1,10-phenanthroline-κ2 N,N′)(2,2,2-trichloroacetato-κO)cobalt(II)
The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro-acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa-hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(-) ion in the equatorial plane and one O atom from the trichloro-acetate ligand and one phenanthroline N ...
متن کاملcatena-Poly[[(nitrato-κO)(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-nitrato-κ2 O:O′]
In the crystal structure of the title compound, [Mn(NO(3))(2)(C(12)H(8)N(2))](n), the Mn(II) atoms are linked by nitrate ligands to form a chain. Each Mn(II) atom is five-coordinated by two N atoms of a 1,10-phenanthroline ligand and three O atoms of two nitrates within a trigonal-bipyramidal coordination geometry. In the crystal structure, the chains are linked by hydrogen bonds into a polymer...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008